Slide 81 Comparison Between Theory and Experiment: H 2 O(g) For molecules with a singlet electronic ground state and no low-lying excited electronic l
{"Image DocumentName": "Comparison Between Theory and Experiment: H2O(g)", "Image ImageDescription": "For molecules with a singlet electronic ground state and no low-lying. excited electronic levels, translations, rotations and vibrations are the. only contributions to the thermodynamic properties. We ll consider water, which has 3 translations, 3 rotations and 3 vibrations. Using Equipartition of Energy, one predicts: Htran = (3/2)RT + RT CPtran = (3/2)R + R = (5/2)R. Hrot = (3/2)RT CProt = (3/2)R. Hvib = 3RT CPvib = 3R. Low T Limit: Htran + Hrot = 4RT CPtran + CProt = 4R. High T Limit: Htran + Hrot + Hvib = 7RT CPtran + CProt + CPvib= 7R.", "Image XResolution": "37", "Image YResolution": "37", "Image ResolutionUnit": "Pixels/Centimeter", "Image Software": "SlidePlayer", "Image YCbCrPositioning": "Centered"}